28 Examples of Toxic Gases in the Workplace You Must Know

toxic gases in the workplace

You must treat the existence of toxic gases in the workplace appropriately. Otherwise, a fatal work accident will occur.

The first thing you should do is to ensure that you know gases that are classified as toxic gases.

After that, you need to identify their existences in the workplace exactly, where the sources are located.

Finally, you must take appropriate countermeasures to these toxic gases in order to eliminate or reduce the releases, monitor them, and alert you when unsafe levels of the gases are detected in the atmosphere.

The Definition of Toxic Gas

For the toxic gas definition, I will use the definition of toxic gas by the NFPA.

According to NFPA, a toxic gas is defined as:

“A gas with a median lethal concentration (LC50) in air of more than 200 ppm but not more than 2000 ppm by volume of gas or vapor, or more than 2 mg/L but not more than 20 mg/L of mist, fume, or dust, when administered by continuous inhalation for 1 hour (or less if death occurs within 1 hour) to albino rats weighing between 0.44 lb and 0.66 lb (200 g and 300 g) each.”

From the above definition, then I take several gases that have health hazard rating from 2 to 4 as the examples.

The health hazard rating by NFPA 704 is

  • 4: deadly
  • 3: extreme danger
  • 2: hazardous
  • 1: slightly hazardous
  • 0: normal material

The examples of toxic gases that you will see in the section below are arranged based on their health hazard ratings.

28 Toxic Gases in the Workplace

After knowing the definition of toxic gas, now we will see some examples of toxic gases that can commonly be found in the workplace.

Be careful when you deal with one of the following toxic gas in the workplace since they are harmful to your health.

Toxic GasChemical FormulaNFPA Toxic Rating
ArsineASH34
DiboraneB2H64
DichlorosilaneH2Cl2Si4
FluorineF24
Hydrogen CyanideHCN4
Hydrogen FluorideHF4
Hydrogen SulfideH2S4
OzoneO34
PhosgeneCOCL24
PhosphinePH34
Sulfur TetrafluorideSF44
AmmoniaNH33
Boron TrichlorideBCl33
Boron TrifluorideBF33
Carbon MonoxideCO3
ChlorineCl23
Dimethylamine(CH3)2NH3
Ethylene OxideC2H4O3
Hydrogen BromideHBr3
Hydrogen ChlorideHCL3
MonomethylamineCH3NH23
Nitric OxideNO3
Nitrogen DioxideNO23
Sulfur DioxideSO23
TrimethylamineC3H9N3
Methyl ChlorideCH3Cl2
Vinyl ChlorideC2H3Cl2

Toxic Gas Accidents in the Workplace

In this final section, I would like to show some work accident data in some countries that associated with toxic gases.

In the US, according to the U.S Bureau of Labor Statistics, there were 297 fatalities across the 7-year span, i.e. from the year 2011 to 2017, caused by toxic gas exposures.

Meanwhile, in Japan work accidents caused by harmful substances – including toxic gases – were responsible for 6% of the total fatalities in 2019, as published by Japan Industrial Safety & Health Association.

In China, gas or chemical exposure was responsible for 9% of the total work accident in 2019, as reported by China Labour Bulletin.

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